Ionic fragmentation of a natural product, limonene (C10H16), following core
Photoionization of the limonene [C10H16] molecule was studied for the first time following C 1s ionization, using synchrotron radiation and time-of-fight mass spectrometry. As a reference for further analysis of the photon induced fragmentation of the limonene molecule, the He(I) mass spectrum was a...
| Autor principal: | Castilho, R. B. de |
|---|---|
| Outros Autores: | Nunez, C. V., Coutinho, Lúcia H., Lago, Alexsandre F., Bernini, Rafael Berrelho, Souza, Gerardo Gerson Bezerra de |
| Grau: | Artigo |
| Idioma: | English |
| Publicado em: |
Journal of Electron Spectroscopy and Related Phenomena
2020
|
| Assuntos: | |
| Acesso em linha: |
https://repositorio.inpa.gov.br/handle/1/18694 |
| id |
oai:repositorio:1-18694 |
|---|---|
| recordtype |
dspace |
| spelling |
oai:repositorio:1-18694 Ionic fragmentation of a natural product, limonene (C10H16), following core C 1s] photoionization Castilho, R. B. de Nunez, C. V. Coutinho, Lúcia H. Lago, Alexsandre F. Bernini, Rafael Berrelho Souza, Gerardo Gerson Bezerra de Kinetic Energy Mass Spectrometry Photoionization Photons Reaction Kinetics Synchrotron Radiation Core Ionization Electron Impact Mass Spectrum Limonene Time-of-flight Mass Spectrometry Organic Compounds Photoionization of the limonene [C10H16] molecule was studied for the first time following C 1s ionization, using synchrotron radiation and time-of-fight mass spectrometry. As a reference for further analysis of the photon induced fragmentation of the limonene molecule, the He(I) mass spectrum was also obtained. Previously unreported singly charged species have been observed at 310 eV: H+, C+, CH+, CH2 +, CH3 +. A close similarity has been observed between the high photon energy mass spectrum and the standard electron impact mass spectrum of limonene, obtained at 70 eV. In particular, the base peak [C5H8 +, m/q = 68], known to result from a Retro Diels-Alder reaction, remains the same in both cases. Approximate values for the mean kinetic energy were determined for all ionic species. © 2006 Elsevier B.V. All rights reserved. 2020-06-15T22:02:36Z 2020-06-15T22:02:36Z 2007 Artigo https://repositorio.inpa.gov.br/handle/1/18694 10.1016/j.elspec.2006.12.020 en Volume 155, Número 1-3, Pags. 77-80 Restrito Journal of Electron Spectroscopy and Related Phenomena |
| institution |
Instituto Nacional de Pesquisas da Amazônia - Repositório Institucional |
| collection |
INPA-RI |
| language |
English |
| topic |
Kinetic Energy Mass Spectrometry Photoionization Photons Reaction Kinetics Synchrotron Radiation Core Ionization Electron Impact Mass Spectrum Limonene Time-of-flight Mass Spectrometry Organic Compounds |
| spellingShingle |
Kinetic Energy Mass Spectrometry Photoionization Photons Reaction Kinetics Synchrotron Radiation Core Ionization Electron Impact Mass Spectrum Limonene Time-of-flight Mass Spectrometry Organic Compounds Castilho, R. B. de Ionic fragmentation of a natural product, limonene (C10H16), following core |
| topic_facet |
Kinetic Energy Mass Spectrometry Photoionization Photons Reaction Kinetics Synchrotron Radiation Core Ionization Electron Impact Mass Spectrum Limonene Time-of-flight Mass Spectrometry Organic Compounds |
| description |
Photoionization of the limonene [C10H16] molecule was studied for the first time following C 1s ionization, using synchrotron radiation and time-of-fight mass spectrometry. As a reference for further analysis of the photon induced fragmentation of the limonene molecule, the He(I) mass spectrum was also obtained. Previously unreported singly charged species have been observed at 310 eV: H+, C+, CH+, CH2 +, CH3 +. A close similarity has been observed between the high photon energy mass spectrum and the standard electron impact mass spectrum of limonene, obtained at 70 eV. In particular, the base peak [C5H8 +, m/q = 68], known to result from a Retro Diels-Alder reaction, remains the same in both cases. Approximate values for the mean kinetic energy were determined for all ionic species. © 2006 Elsevier B.V. All rights reserved. |
| format |
Artigo |
| author |
Castilho, R. B. de |
| author2 |
Nunez, C. V. Coutinho, Lúcia H. Lago, Alexsandre F. Bernini, Rafael Berrelho Souza, Gerardo Gerson Bezerra de |
| author2Str |
Nunez, C. V. Coutinho, Lúcia H. Lago, Alexsandre F. Bernini, Rafael Berrelho Souza, Gerardo Gerson Bezerra de |
| title |
Ionic fragmentation of a natural product, limonene (C10H16), following core |
| title_short |
Ionic fragmentation of a natural product, limonene (C10H16), following core |
| title_full |
Ionic fragmentation of a natural product, limonene (C10H16), following core |
| title_fullStr |
Ionic fragmentation of a natural product, limonene (C10H16), following core |
| title_full_unstemmed |
Ionic fragmentation of a natural product, limonene (C10H16), following core |
| title_sort |
ionic fragmentation of a natural product, limonene (c10h16), following core |
| publisher |
Journal of Electron Spectroscopy and Related Phenomena |
| publishDate |
2020 |
| url |
https://repositorio.inpa.gov.br/handle/1/18694 |
| _version_ |
1787141155035545600 |
| score |
11.755432 |